Water oxidation catalyzed by molecular di- and nonanuclear Fe complexes: importance of a proper ligand framework.
نویسندگان
چکیده
The synthesis of two molecular iron complexes, a dinuclear iron(iii,iii) complex and a nonanuclear iron complex, based on the dinucleating ligand 2,2'-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the one-electron oxidant [Ru(bpy)3](3+).
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ورودعنوان ژورنال:
- Dalton transactions
دوره 45 34 شماره
صفحات -
تاریخ انتشار 2016